Application Question
Medium difficulty • Concept in a practical situation
Question 1
Applied ConceptA solar cell made of caesium (work function 2.14 eV) is exposed to sunlight containing photons of various frequencies. With reference to Einstein's photoelectric equation, explain under what condition the cell will produce photocurrent and determine the threshold wavelength above which the cell will not respond.
- The solar cell will produce photocurrent only when the frequency of incident photons exceeds the threshold frequency ν₀ = φ₀/h = 2.14 eV / 6.626 × 10⁻³⁴ J s ≈ 5.16 × 10¹⁴ Hz. Photons below this frequency have insufficient energy to eject electrons regardless of intensity.
- The threshold wavelength is λ₀ = c/ν₀ = (3 × 10⁸ m/s) / (5.16 × 10¹⁴ Hz) ≈ 581 nm. Incident radiation with wavelength greater than 581 nm (lower frequency, lower photon energy) will not cause photoelectric emission in caesium.
- Caesium being an alkali metal has a relatively low work function, making it sensitive to visible light. Sunlight contains substantial radiation below 581 nm (blue, violet, UV), so the caesium solar cell will respond to these components and produce photocurrent proportional to their intensity.